It is doubtful that some 'one-click' apk to exe converter or apk to exe emulator exist (although you can find dubious apps like apk2exe), and you should be extra wary of online converters that advertise this as a such websites might yield files infected with some malware or ransomware or are just some kind of scam. APKs are the choice format for the Google Android platform, and EXE files are associated with Windows. Directly exporting Android APK archives to EXE executables is not very likely because both formats are meant for different platforms.
As far as we know, no way to achieve apk to exe conversion exists.